Content for NMR-STAR saveframe, "chemical_shift_assignment_set_four"

    save_chemical_shift_assignment_set_four
   _Assigned_chem_shift_list.Sf_category                   assigned_chemical_shifts
   _Assigned_chem_shift_list.Sf_framecode                  chemical_shift_assignment_set_four
   _Assigned_chem_shift_list.Entry_ID                      4001
   _Assigned_chem_shift_list.ID                            4
   _Assigned_chem_shift_list.Sample_condition_list_ID      1
   _Assigned_chem_shift_list.Sample_condition_list_label  $sample_conditions_one
   _Assigned_chem_shift_list.Chem_shift_reference_ID       1
   _Assigned_chem_shift_list.Chem_shift_reference_label   $chemical_shift_reference_one
   _Assigned_chem_shift_list.Chem_shift_1H_err             .
   _Assigned_chem_shift_list.Chem_shift_13C_err            .
   _Assigned_chem_shift_list.Chem_shift_15N_err            .
   _Assigned_chem_shift_list.Chem_shift_31P_err            .
   _Assigned_chem_shift_list.Chem_shift_2H_err             .
   _Assigned_chem_shift_list.Chem_shift_19F_err            .
   _Assigned_chem_shift_list.Error_derivation_method       .
   _Assigned_chem_shift_list.Details                      
;
This save frame contains one set of peak assignments for the protein segment
  from residues 1 to 15. Multiple resonances were not reported for all
  residues in this segment.
;
   _Assigned_chem_shift_list.Text_data_format              .
   _Assigned_chem_shift_list.Text_data                     .

   loop_
      _Chem_shift_experiment.Experiment_ID
      _Chem_shift_experiment.Experiment_name
      _Chem_shift_experiment.Sample_ID
      _Chem_shift_experiment.Sample_label
      _Chem_shift_experiment.Sample_state
      _Chem_shift_experiment.Entry_ID
      _Chem_shift_experiment.Assigned_chem_shift_list_ID

      . . 1 $sample_one . 4001 4 

   stop_

   loop_
      _Atom_chem_shift.ID
      _Atom_chem_shift.Assembly_atom_ID
      _Atom_chem_shift.Entity_assembly_ID
      _Atom_chem_shift.Entity_ID
      _Atom_chem_shift.Comp_index_ID
      _Atom_chem_shift.Seq_ID
      _Atom_chem_shift.Comp_ID
      _Atom_chem_shift.Atom_ID
      _Atom_chem_shift.Atom_type
      _Atom_chem_shift.Atom_isotope_number
      _Atom_chem_shift.Val
      _Atom_chem_shift.Val_err
      _Atom_chem_shift.Assign_fig_of_merit
      _Atom_chem_shift.Ambiguity_code
      _Atom_chem_shift.Occupancy
      _Atom_chem_shift.Resonance_ID
      _Atom_chem_shift.Auth_entity_assembly_ID
      _Atom_chem_shift.Auth_asym_ID
      _Atom_chem_shift.Auth_seq_ID
      _Atom_chem_shift.Auth_comp_ID
      _Atom_chem_shift.Auth_atom_ID
      _Atom_chem_shift.Details
      _Atom_chem_shift.Entry_ID
      _Atom_chem_shift.Assigned_chem_shift_list_ID

       1 . 1 1 4 4 LEU HA   H  1   4.04 . . 1 . . . . . . . . 4001 4 
       2 . 1 1 4 4 LEU HB2  H  1   1.89 . . 2 . . . . . . . . 4001 4 
       3 . 1 1 4 4 LEU HB3  H  1   1.75 . . 2 . . . . . . . . 4001 4 
       4 . 1 1 4 4 LEU HG   H  1   1.21 . . 1 . . . . . . . . 4001 4 
       5 . 1 1 4 4 LEU HD11 H  1   0.99 . . 2 . . . . . . . . 4001 4 
       6 . 1 1 4 4 LEU HD12 H  1   0.99 . . 2 . . . . . . . . 4001 4 
       7 . 1 1 4 4 LEU HD13 H  1   0.99 . . 2 . . . . . . . . 4001 4 
       8 . 1 1 4 4 LEU HD21 H  1   0.75 . . 2 . . . . . . . . 4001 4 
       9 . 1 1 4 4 LEU HD22 H  1   0.75 . . 2 . . . . . . . . 4001 4 
      10 . 1 1 4 4 LEU HD23 H  1   0.75 . . 2 . . . . . . . . 4001 4 
      11 . 1 1 4 4 LEU H    H  1   8.92 . . 1 . . . . . . . . 4001 4 
      12 . 1 1 4 4 LEU C    C 13 178.46 . . 1 . . . . . . . . 4001 4 
      13 . 1 1 4 4 LEU CA   C 13  58.62 . . 1 . . . . . . . . 4001 4 
      14 . 1 1 4 4 LEU CB   C 13  41.93 . . 1 . . . . . . . . 4001 4 
      15 . 1 1 4 4 LEU CG   C 13  29.00 . . 1 . . . . . . . . 4001 4 
      16 . 1 1 4 4 LEU CD1  C 13  26.92 . . 2 . . . . . . . . 4001 4 
      17 . 1 1 4 4 LEU CD2  C 13  26.4  . . 2 . . . . . . . . 4001 4 
      18 . 1 1 4 4 LEU N    N 15 121.62 . . 1 . . . . . . . . 4001 4 
      19 . 1 1 6 6 LYS HA   H  1   3.9  . . 1 . . . . . . . . 4001 4 
      20 . 1 1 6 6 LYS HB2  H  1   1.89 . . 1 . . . . . . . . 4001 4 
      21 . 1 1 6 6 LYS HB3  H  1   1.89 . . 1 . . . . . . . . 4001 4 
      22 . 1 1 6 6 LYS HG2  H  1   1.48 . . 1 . . . . . . . . 4001 4 
      23 . 1 1 6 6 LYS HG3  H  1   1.48 . . 1 . . . . . . . . 4001 4 
      24 . 1 1 6 6 LYS HD2  H  1   1.73 . . 1 . . . . . . . . 4001 4 
      25 . 1 1 6 6 LYS HD3  H  1   1.73 . . 1 . . . . . . . . 4001 4 
      26 . 1 1 6 6 LYS HE2  H  1   2.98 . . 1 . . . . . . . . 4001 4 
      27 . 1 1 6 6 LYS HE3  H  1   2.98 . . 1 . . . . . . . . 4001 4 
      28 . 1 1 6 6 LYS H    H  1   8.51 . . 1 . . . . . . . . 4001 4 
      29 . 1 1 6 6 LYS C    C 13 179.8  . . 1 . . . . . . . . 4001 4 
      30 . 1 1 6 6 LYS CA   C 13  60.31 . . 1 . . . . . . . . 4001 4 
      31 . 1 1 6 6 LYS CB   C 13  32.72 . . 1 . . . . . . . . 4001 4 
      32 . 1 1 6 6 LYS CG   C 13  25.87 . . 1 . . . . . . . . 4001 4 
      33 . 1 1 6 6 LYS CD   C 13  29.53 . . 1 . . . . . . . . 4001 4 
      34 . 1 1 6 6 LYS CE   C 13  36.31 . . 1 . . . . . . . . 4001 4 
      35 . 1 1 6 6 LYS N    N 15 117.59 . . 1 . . . . . . . . 4001 4 

   stop_

save_